Ethanol Gas Detection Using a Yolk-Shell (Core-Shell) α-Fe2O3 Nanospheres as Sensing Material

作者: Lili Wang ,Zheng Lou ,Jianan Deng ,Rui Zhang ,Ton
期刊: ACS Appl. Mat. Interfaces
卷号: 2015,7(23),13098-13104
接收日期: 2015-05-27 17:59:40
摘要 Abstract

Abstract

Three-dimensional (3D) nanostructures of α-Fe 2 O 3   materials , including both hollow sphere-shaped and  yolk-shell  ( core-shell )-shaped, have been successfully synthesized via an environmentally friendly hydrothermal approach. By expertly adjusting the reaction time, the solid, hollow, and  yolk-shell  shaped α-Fe 2 O 3  can be selectively synthesized.  Yolk-shell  α-Fe 2 O 3 nanospheres  display outer diameters of 350 nm, and the interstitial hollow spaces layer is intimately sandwiched between the inner and outer  shell  of α-Fe 2 O 3  nanostructures. The possible growth mechanism of the  yolk-shell nanostructure is proposed. The results showed that the well-defined bilayer interface effectively enhanced the  sensing  performance of the α-Fe 2 O 3 nanostructures (i.e.,  yolk-shell  α-Fe 2 O 3 @α-Fe 2 O 3 ), owing predominantly to the unique nanostructure, thus facilitated the transport rate and augmented the adsorption quantity of the target  gas  molecule under  gas detection .



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