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我课题组文章“Improved and excellent humidity sensitivities based on KCl-doped TiO2 electrospun nanofibers,” (Qi Qi, Tong Zhang, Lijie Wang, Appl. Phys. Lett. 2008, 93 (2), 023105)和“Humidity sensing properties of KCl-doped ZnO nanofibers with super-rapid response and recovery(Qi Qi,Tong Zhang,Shujuan Wang,Xuejun Zheng, Sens. Actuators B 2009, 137, 649-655)Chem. Soc. Rev. (2011, 40, 2417-2434)引用,引文如下:

These excellent features were also observed in separate studies,    for instance by Zhang et al. 81who used Na+ -doped ZnO nanofiber membranes and by Qi et al. 82 who used KCl-doped TiO2 nanofibers. A clear breakthrough was made by    the same group in 2009 using KCl-doped ZnO electrospun nanofibers. 79 For 5.7 wt% KCl-doped ZnO fibers, having diameters    of approximately 500 nm, very rapid response (2 s) and recovery times (1 s)    could be achieved (Fig. 13). This enhanced response rate was likely due to    the intrinsic characteristics of the materials used, with ZnO having excellent electrical and piezoelectrical properties and potassium ions which    further augment the ionic conduction. 

我课题组文章“Zinc oxide coreshell hollow microspheres with multi-shelled architecture for gas sensor applications (Lili Wang, Zheng Lou, Teng Fei, Tong Zhang, (J. Mater. Chem. 2011, 21, 19331-19336)Chem. Soc. Rev. (2013, 42, 2610-2653)引用,引文如下:

There are also many examples of templated synthesis through precipitation reactions. In these cases, precipitated materials    nucleate around a template and grow into a shell. Zhang et al. reported the    synthesis of ZnO hollow structures using Zn(Ac)2 and ammonia as    precursors and carbon spheres as templates.55 Recently, Wang et al. reported the successful synthesis of    Au–Cu2O core–shell nanostructures with novel optical properties    by precipitation and reduction of Cu2+ templated on AuNPs.56 Zhang et al.reported a synthesis for hollow spheres of Y2O3 with and without metal dopants by urea assisted coprecipitation of Y(NO3)3 and dopant nitrate.57 

我课题组文章“Enhanced acetone sensing performances of hierarchical hollow Au-loaded NiO hybrid structures” (Lili Wang, Zheng Lou, Teng Fei, Tong Zhang, Sens. Actuators B 2012, 161, 178-183)Ring-like PdO-decorated NiO with lamellar structures and their application in gas sensor” (Lili Wang, Zheng Lou, Rui Wang, Teng Fei, Tong Zhang, Sens. Actuators B 2012,171-172,1180-1185)Jong-Heun Lee Sens. Actuators B发表的“Highly sensitive and selective gas sensors using p-type oxide semiconductors: Overview (2014, 192, 607–627)做了正面评价和引用,引文如下:

The gas response of p-type oxide    semiconductors also increases by loading noble metals. The relevant results    in the literature are summarized in Table 3 [24, 30, 121–124] .Wang et al. previously reported that decorating PdO onto ring-like NiO nanostructures enhanced    the response (Rg/Ra) of the sensor to 20 ppm CO from 8.2    to 27.5 [30] .They [122] also reported that the response of hierarchical    hollow NiO nanostructures to CH3COCH3 can be enhanced to 6.7 times by loading the nanostructures with Au nanoparticles. One of the present authors    [24] previously demonstrated that loading Pt nanoparticles onto both the    inner and outer walls of thin NiO tubes can enhance the response (Rg/Ra) to 100 ppm C2H5OH from 1.69 to 11.7. It is noteworthy that in all three studies, the    selectivity of the oxide semiconductor sensors to CO, CH3COCH3,    and C2H5OH was also enhanced [24, 30, 122],    indicating the chemical sensitization of noble metals or noble metal    oxides. 

我课题组文章Synthesis and characterization of TiO2 nanotubes for humidity sensing (Appl. Surf. Sci. (Yanyan Zhang, Wuyou Fu, Haibin Yang, Qi Qi, Yi Zeng, Tong Zhang, Ruixia Ge, Guangtian Zou, Appl. Surf. Sci., 2008, 254, 5545-5547)ACS NANO (2011, 5, 1967-1974)引用,引文如下:

There have been a    few reports on neat TiO2 films or nanostructures acting as    humidity sensors.53,54,56 Zhang et al.    reported a resistive humidity sensor from a TiO2 nanotube array,    and it was tested with different calcination temperatures.54 The    calcination temperature affects the crystal form of TiO2, and    rutile form provided the best results for sensing. A sample calcinated at    600 oC gave the best response with response times of 100 and 190    s for dry (5%) and humid (95%) air. 

我课题组文章Study on humidity sensing properties based on composite materials of Li-doped mesoporous silica A-SBA-15 (Tong Zhang, Rui Wang, Wangchang Geng, Xiaotian Li, Qi Qi, Yuan He, Shujuan Wang, Sens. Actuators B, 2008, 128, 482-487)Chem. Soc. Rev. (2013, 42, 4036-4053)引用,引文如下:

Loading mesoporous    SBA-15 silica with LiCl was also shown to result in improved humidity    sensing characteristics (better linearity, shorter response–recovery    times), explainable by the hydrophilic property of Li+.178 This was further investigated by using    LiCl-modified SBA-15 silica in higher structural quality; proton conduction    was found to be dominating at low relative humidity whereas ionic    contributions (LiCl) become relevant at high humidity.

 

我课题组文章Fabrication of N-type Fe2O3 and P-type LaFeO3 nanobelts by electrospinning and determination of gas-sensing properties (Huitao Fan, Tong Zhang, Xiujuan Xu, Ning Lv, Sens. Actuators B, 2011, 153, 83-88), An excellent humidity sensor with rapid response based on BaTiO3 nanofiber via electrospinning (Yuan He, Xiangwei Liu, Rui Wang, Tong Zhang, Sens. Lett., 2011, 9, 262-265) 以及DC humidity sensing properties of BaTiO3 nanofiber sensors with different electrode materials(Lijie Wang, Yuan He, Jiahuan Hu, Qi Qi, Tong Zhang, Sens. Actuators B, 2011, 153, 460-464)Prog. Polym. Sci.(2013, 38, 963-991)引用,引文如下:

N-type Fe2O3 nanobelts and P-type LaFeO3 nanobelts were prepared by electrospinning, the evaluation showing that the    optimum operating temperature of the gas sensors fabricated from Fe2O3 nanobelts is 285 ◦C, whereas that from the LaFeO3 nanobelts amounts to 170 ◦C [215].  An impedance-type humidity sensor was    fabricated based on the BaTiO3 nanofiber [218,219]. The    impedance-type humidity sensor exhibited a fast response/recovery property.

 

我课题组文章Encapsuled nanoreactors (Au@SnO2): a new sensing material for chemical sensors (Lili Wang, Huimin Dou, Zheng Lou, Tong Zhang, Nanoscale 2013, 5, 2696-2691)Prog. Mater. Sci.引用,引文如下:

SnO2 powder, thin film, nanostructure, especially nanowires are integrated in    sensing devices. For this thick pastes of the SnO2 nanostructures    (nanorod, spheres, pyramid, etc.) are prepared in an aqueous medium    containing a small amount of polyvinylalcohol (PVA) binder. The pastes were    painted on the outer surface of alumina tubes (length 3 mm, outer diameter    2 mm and thickness 0.5 mm). Gold electrodes and platinum lead wires were    attached at the ends of the tubes (by curing at a higher temperature)    before applying the paste [810].

 

我课题组文章Three-Dimensional Hierarchical Flowerlike α-Fe2O3 Nanostructures: Synthesis and Ethanol-Sensing Properties (Lili Wang, Teng Fei, Zheng Lou, Tong Zhang, ACS Appl. Mater. Interfaces 2011, 3, 4689-4694)J. Am. Chem. Soc.引用,引文如下:

Therefore,    the above results demonstrate that ultrathin α-Fe2O3 nanosheets with half-unitcell thickness are successfully synthesized. In    comparison with the previous reports of α-Fe2O nanosheets with thickness ranging from several to tens of nanometers,22−26 the    success of our template-assisted oriented growth lies in the interacting    promotion of CuO self-dissolution and Fe ion hydrolysis that makes the    nanosheets intensively adjacent on the template surface to orient the    growth and the low growth temperature that can effectively inhibit the    growth of nanosheets along the third dimension.

 

我课题组文章Synthesis of rattle-type SnO2 structures with porous shell (Lili Wang, Teng Fei, Jianan Deng, Zheng Lou, Rui Wang, Tong Zhang, J. Mater. Chem. 2012, 22, 18111-18114)Amitava Patra J. Am. Chem. C发表的Recent development of core–shell SnO2 nanostructures and their potential applications (2014, 2, 6706–6722)做了正面评价和引用,引文如下:

Zhang et    al.58 have reported an innovative hydrothermal shell-by-shell    templating strategy appropriate for the preparation of SnO2 rattle-type    nanospheres. First, they have used an organic capping agent (PVP) to    anchor the SiO2 nanoparticles and prevent the aggregation of    nanoparticles in solution. Then, the SnO2 nanospheres were    coated with silica and used as templates to prepare SnO2 rattle-type nanospheres. The fabrication process is a three-step procedure,    and each step is well controlled (Fig. 1b). Peng et al.34 have used a    hydrothermal process for the synthesis of TiO2 coated SnO2 nanotubes with different SnO2 contents. It is clear from the    above discussion that the hydrothermal method is an effective approach for    the synthesis of SnO2-based core–shell nanoparticles.